Condensed Matter Physics, 1997, No 9, p. 137-148, English
<BR>
<A HREF="https://doi.org/10.5488/CMP.9.137"> DOI:10.5488/CMP.9.137</A>

<HR>
<B>Title: </B> THE CENTRAL FORCE WATER MODEL AT THE ELECTROLYTE-ELECTRODE 
INTERFACE: AN INTEGRAL EQUATION APPROACH <BR>

<B>Authors: </B>M.Vossen, F.Forstmann, A.Kraemer (Institut fuer 
Theoretische Physik, Freie Universitaet Berlin, Arnimallee 14, D-14195 
Berlin, Germany) 

<p>
<blockquote>
The central force water model is well suited for integral equation methods. 
At the electrode surface we find water molecules arranged in an ice-like 
structure with a surface dipole pointing towards the liquid and a negative 
surface potential -0.11 V at zero electrode charge. We find an asymmetric 
differential capacitance due to the water structure. Added Na^+ and Cl^- 
ions do not destroy the water structure. Only the small Na^+ can penetrate 
the structured water layer at high negative electrode charge.
</blockquote>
<B>Comments: </B>Figs. 9, Refs. 26, Tabs. 0.<BR>

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