MODEL PSEUDOPOTENTIAL OF THE ELECTRON - NEGATIVE ION
Author(s): Yu.Rudavskii, G.Ponedilok, M.Klapchuk (National University ``Lvivska Politechnika'' 12~S.Bandera Str., 79013 Lviv, Ukraine)
Generalization of the Anderson model to describe the states of electronegative impurities in liquid-metal alloys is the main aim of the present paper. The effects of the random inner field on the charge impurity states is accounted for selfconsistently. Qualitative and quantitative estimation of hamiltonian parameters has been carried out. The limits of the proposed model applicability to a description of real systems are considered. Especially, the case of the oxygen impurity in liquid sodium is studied. The modelling of the proper electron-ionic interaction potential is the main goal of the paper. The parameters of the proposed pseudopotential are analyzed in detail. The comparison with other model potentials have been carried out. Resistivity of liquid sodium containing the oxygen impurities is calculated with utilizing the form-factor of the proposed model potential. Dependence of the resistivity on impurity concentration and on the charge states is received.
Key words: liquid metals, electronegative impurity, Anderson model
PACS: 71.23.-k, 71.23.An, 72.15.Rn
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