Condensed Matter Physics, 2006, vol. 9, No. 1(45), p. 55-63, English
DOI:10.5488/CMP.9.1.55

Title: Quantum kinetic equations approach to the description of chemical reactions between adparticles at a metallic surface
Author(s):
  V.V.Ignatyuk (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine) ,
  M.V.Tokarchuk (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine) ,
  P.P.Kostrobij (Lviv Polytechnic National University, Bandery Str.12, Lviv, Ukraine)

Adparticle dynamics at a metallic surface is studied by means of quantum kinetic equations. Kinetic equations of the reaction-diffusion type are written down for nonequilibrium one-particle distribution functions of the adsorbate up to the second order in the tunnelling constants and amplitudes of chemical reactions.

Key words: quantum kinetic theory, models of surface chemical reactions, diffusion coefficient, rate constant
PACS: 05.60.Gg, 05.70.Np, 63.10.+a, 68.43, 82.20.Xr


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