Condensed Matter Physics, 2006, vol. 9, No. 1(45), p. 55-63, English
DOI:10.5488/CMP.9.1.55
Title:
Quantum kinetic equations approach to the description of
chemical reactions between adparticles at a metallic surface
Author(s):
 
| V.V.Ignatyuk
(Institute for Condensed Matter
Physics of the National Academy of Sciences of Ukraine, 1
Svientsitskii Str., 79011 Lviv, Ukraine)
,
|
 
| M.V.Tokarchuk
(Institute for Condensed Matter
Physics of the National Academy of Sciences of Ukraine, 1
Svientsitskii Str., 79011 Lviv, Ukraine)
,
|
 
| P.P.Kostrobij
(Lviv Polytechnic National University, Bandery Str.12, Lviv, Ukraine)
|
Adparticle dynamics at a metallic surface is studied by means of
quantum kinetic equations. Kinetic equations of the
reaction-diffusion type are written down for nonequilibrium
one-particle distribution functions of the adsorbate up to the
second order in the tunnelling constants and amplitudes of
chemical reactions.
Key words: quantum kinetic theory, models of surface chemical
reactions, diffusion coefficient, rate constant
PACS: 05.60.Gg, 05.70.Np, 63.10.+a, 68.43, 82.20.Xr
|