Condensed Matter Physics, 2008, vol. 11, No. 4(56), p. 663-667
DOI:10.5488/CMP.11.4.663

Title: Phase transitions in the lattice model of intercalation
Author(s):
  T.S. Mysakovych (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine) ,
  V.O. Krasnov (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine) ,
  I.V. Stasyuk (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine)

The lattice model which can be employed for the description of intercalation of ions in crystals is considered in this work. Pseudospin formalism is used in describing the interaction of electrons with ions. The possibility of hopping of intercalated ions between different positions is taken into account. The thermodynamics of the model is investigated in the mean field approximation. Phase diagrams are built. It is shown that at high values of the parameter of ion transfer, the phase transition to a modulated phase disappears.

Key words: intercalation, phase transition, pseudospin-electron model
PACS: 64.75.+g, 71.20.Tx, 64.70.-p


Full text [pdf, ps] << List of papers