Condensed Matter Physics, 2011, vol. 14, No. 1, 13603: 1-12
DOI:10.5488/CMP.14.13603           arXiv:1106.3236

Title: The liquid-vapor interface of the restricted primitive model of ionic fluids from a density functional approach
Author(s):
  A. Patrykiejew (Department for the Modelling of Physico-Chemical Processes, Maria Curie-Skłodowska University, 20 – 031 Lublin, Poland, ) ,
  S. Sokołowski (Department for the Modelling of Physico-Chemical Processes, Maria Curie-Skłodowska University, 20 – 031 Lublin, Poland, ) ,
  O. Pizio (Instituto de Química de la UNAM, Coyoacán 04510, México )

We investigate the liquid-vapor interface of the restricted primitive model for an ionic fluid using a density functional approach. The applied theory includes the electrostatic contribution to the free energy functional arising from the bulk energy equation of state and the mean spherical approximation for a restricted primitive model, as well as the associative contribution, due to the formation of pairs of ions. We compare the density profiles and the values of the surface tension with previous theoretical approaches.

Key words: density functional, adsorption, chains, crystals
PACS: 68.08.-p, 68.43.Fg, 82.35.Gh, 68.43.-h
Comments: Figs. 8, Refs. 48


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