Condensed Matter Physics, 2018, vol. 21, No. 2, 23801
DOI:10.5488/CMP.21.23801           arXiv:1806.09960

Title: Spatiotemporal pattern formation in a three-variable CO oxidation reaction model
Author(s):
  I.S. Bzovska (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv, Ukraine) ,
  I.M. Mryglod (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv, Ukraine)

The spatiotemporal pattern formation is studied in the catalytic carbon monoxide oxidation reaction that takes into account the diffusion processes over the Pt(110) surface, which may contain structurally different areas. These areas are formed during CO-induced transition from a reconstructed phase with 1×2 geometry of the overlayer to a bulk-like (1×1) phase with square atomic arrangement. Despite the CO oxidation reaction being non-autocatalytic, we have shown that the analytic conditions of the existence of the Turing and the Hopf bifurcations can be satisfied in such systems. Thus, the system may lose its stability in two ways — either through the Hopf bifurcation leading to the formation of temporal patterns in the system or through the Turing bifurcation leading to the formation of regular spatial patterns. At a simultaneous implementation of both scenarios, spatiotemporal patterns for CO and oxygen coverages are obtained in the system.

Key words: reaction-diffusion model, spatiotemporal patterns, the Hopf bifurcation, the Turing bifurcation
PACS: 82.40.Bj, 82.45.Jn


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