Condensed Matter Physics, 2009, vol. 12, No. 2, pp. 295-317
DOI:10.5488/CMP.12.2.295

Title: The effect of transverse electric fields on dielectric, piezoelectric, elastic and thermal properties of the Rochelle salt NaKC4H4O6 · 4H2O
Author(s):
  R.R. Levitskii (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine) ,
  I.R. Zachek (Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine) ,
  A.S. Vdovych (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine) ,
  I.V. Stasyuk (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011 Lviv, Ukraine)

Modified four-sublattice model for Rochelle salt by taking into account piezoelectric interactions with shear strain ε4 , ε5 and ε6 is proposed. Components of polarization vector and static dielectric permittivity tensor for both mechanically clamped and free crystals, their piezoelectric characteristics and elastic modules are derived in the mean field approximation. A comprehensive study of transverse field effect on phase transition temperatures, dielectric and elastic properties of Rochelle salt has been performed for the first time.

Key words: ferroelectrics, rochelle salt, piezoelectric modules
PACS: 77.84.-s, 64.60.Cn, 77.22.-d, 77.80.-e, 77.80.Bh, 77.65.Bn
Comments: Figs. 15, Refs. 50, Tabs. 2


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