Condensed Matter Physics, 2014, vol. 17, No. 4, 43702
DOI:10.5488/CMP.17.43702           arXiv:1501.02571

Title: Thermodynamic and dynamic dielectric properties of one-dimensional hydrogen bonded ferroelectric of PbHPO4<\sub>-type
Author(s):
  I.R. Zachek (Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine) ,
  R.R. Levitskii (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine) ,
  Ya. Shchur (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine) ,
  O.B. Bilenka (Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine)

Within the modified model of proton ordering of one-dimensional ferroelectric having hydrogen bonds of PbHPO4-type, their thermodynamic and dynamic characteristics are studied and calculated taking into account the linear (by crystal deformations ϵi (i=1,3) and ϵ4) contributions into the energy of a proton system but without taking into account the tunneling in the two-particle cluster approximation. There has been obtained a good quantitative description of the temperature dependence of polarization, static dielectric permittivity, heat capacity and frequency dependence of dynamic dielectric permittivity at different temperatures for PbHPO4 and PbHDO4 crystals.

Key words: : ferroelectric, dielectric permittivity, piezoelectric coefficient, PbHPO4
PACS: 77.22.Ch, 77.22.Gm, 77.65.Bn 77.84.Fa, 77.65.Fs


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