Condensed Matter Physics, 2014, vol. 17, No. 4, 43703
DOI:10.5488/CMP.17.43703           arXiv:1502.02399

Title: Electrocaloric effect in KH2PO4 family crystals
Author(s):
  A.S. Vdovych (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine) ,
  A.P. Moina (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine) ,
  R.R. Levitskii (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine) ,
  I.R. Zachek (Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine)

The proton ordering model for the KH2PO4 type ferroelectrics is modified by taking into account the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle cluster approximation we calculate the crystal polarization and explore the electrocaloric effect. Smearing of the ferroelectric phase transition by a longitudinal electric field is described. A good agreement with experiment is obtained.

Key words: electrocaloric effect, KDP, cluster approximation, polarization
PACS: 77.84.Fa, 77.70.+a


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