Condensed Matter Physics, 2016, vol. 19, No. 4, 43705
DOI:10.5488/CMP.19.43705           arXiv:1612.07219

Title: BBGKY chain of kinetic equations, non-equilibrium statistical operator method and collective variable method in the statistical theory of non-equilibrium liquids
Author(s):
  I.R. Yukhnovskii (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv, Ukraine) ,
  P.A. Hlushak (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv, Ukraine) ,
  M.V. Tokarchuk (Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv, Ukraine)

A chain of kinetic equations for non-equilibrium one-particle, two-particle and s-particle distribution functions of particles which take into account nonlinear hydrodynamic fluctuations is proposed. The method of Zubarev non-equilibrium statistical operator with projection is used. Nonlinear hydrodynamic fluctuations are described with non-equilibrium distribution function of collective variables that satisfies generalized Fokker-Planck equation. On the basis of the method of collective variables, a scheme of calculation of non-equilibrium structural distribution function of collective variables and their hydrodynamic speeds (above Gaussian approximation) contained in the generalized Fokker-Planck equation for the non-equilibrium distribution function of collective variables is proposed. Contributions of short- and long-range interactions between particles are separated, so that the short-range interactions (for example, the model of hard spheres) are described in the coordinate space, while the long-range interactions — in the space of collective variables. Short-ranged component is regarded as basic, and corresponds to the BBGKY chain of equations for the model of hard spheres.

Key words: non-linear fluctuations, non-equilibrium statistical operator, distribution function, Fokker–Planck equation, simple fluid
PACS: 74.40.Gh, 05.70.L, 64.70.F


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